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Page 4 of 4 Acidity, electrophilic substitution reactions (halogenation, nitration and sulphonation); Reimer-Tieman reaction, Kolbe reaction. Characteristic reactions of the following (including those mentioned above): Alkyl halides: rearrangement reactions of alkyl carbocation, Grignard reactions, nucleophilic substitution reactions; Alcohols: esterification, dehydration and oxidation, reaction with sodium, phosphorus halides, ZnCl2/concentrated HCl, conversion of alcohols into aldehydes and ketones; Ethers:Preparation by Williamson's Synthesis; Aldehydes and Ketones: oxidation, reduction, oxime and hydrazone formation; aldol condensation, Perkin reaction; Cannizzaro reaction; haloform reaction and nucleophilic addition reactions (Grignard addition); Carboxylic acids: formation of esters, acid chlorides and amides, ester hydrolysis; Amines: basicity of substituted anilines and aliphatic amines, preparation from nitro compounds, reaction with nitrous acid, azo coupling reaction of diazonium salts of aromatic amines, Sandmeyer and related reactions of diazonium salts; carbylamine reaction; Haloarenes: nucleophilic aromatic substitution in haloarenes and substituted haloarenes (excluding Benzyne mechanism and Cine substitution). Carbohydrates: Classification; mono- and di-saccharides (glucose and sucrose); Oxidation, reduction, glycoside formation and hydrolysis of sucrose. Amino acids and peptides: General structure (only primary structure for peptides) and physical properties. Properties and uses of some important polymers: Natural rubber, cellulose, nylon, teflon and PVC. Practical organic chemistry: Detection of elements (N, S, halogens); Detection and identification of the following functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl, amino and nitro; Chemical methods of separation of mono-functional organic compounds from binary mixtures. APTITUDE SYLLABUS
For B.Arch and B.Des Programs Freehand Drawing: This would comprise of simple drawing depicting the total object in its right form and proportion, surface texture, relative location and details of its component parts in appropriate scale. Common domestic or day-to-day life usable objects like furniture, equipment, etc., from memory. Geometrical Drawing: Exercises in geometrical drawing containing lines, angles, triangles, quadrilaterals, polygons, circles etc. Study of plan (top view), elevation (front or side views) of simple solid objects like prisms, cones, cylinders, cubes, splayed surface holders etc. Three-dimensional Perception: Understanding and appreciation of three-dimensional forms with building elements, colour, volume and orientation. Visualization through structuring objects in memory. Imagination and Aesthetic Sensitivity: Composition exercise with given elements. Context mapping. Creativity check through innovative uncommon test with familiar objects. Sense of colour grouping or application. Architectural Awareness: General interest and awareness of famous architectural creations both national and international, places and personalities (architects, designers etc. ) in the related domain. Candidates are advised to bring geometry box sets, pencils, erasers and colour pencils or crayons for the Aptitude Test.
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